Maybe take them out of RAID mode to do the firmware update?
So, yes, this is what I had to do. I absolutely do NOT recommend this method, not without a full (and tested) backup, AND your Windows OS must NOT be on the RAID array. Note that this is for RAID0 - other types should be much simpler by their very nature.
Install a copy of EaseUS Partition Master (home edition is probably good enough).
Get a copy of unetbootin and use it to create bootable USB from Samsung firmware ISO.
Reboot and enter BIOS: break the RAID array, disable secure boot, set to boot from USB.
Reboot, follow prompts to update firmware, remove USB at end.
Reboot and enter BIOS: remove single disk from broken array, create new array.
Reboot and enter Windows.
Use disk manager to init the disk.
Use EaseUS partition recovery wizard.
All done. Check your data, not just the file/folder structure but the actual data.
The above is general guidance only, follow at your own risk, sorry but I can't help you if it all goes horribly wrong.