SATA & PCIE 3.0 x 4 mode or PCIE 3.0 x 4 mode

Nov 26, 2018
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I have a Asus ROG Maximus XI Formula motherboard which comes with two m.2 slots.
1 x M.2 Socket 3, with M key, type 2242/2260/2280/22110 storage devices support (SATA & PCIE 3.0 x 4 mode)*2
1 x M.2 Socket 3, with M key, type 2242/2260/2280 storage devices support (PCIE 3.0 x 4 mode)
Which slot should I connect my Samsung SSD 970 Pro to if I want to boost my Windows 10 from?
Note stats (*2 When M.2_1 Socket 3 is operating in SATA mode, SATA port 2 will be disabled.
When an 22110 M.2 SSD is installed in M.2_1, M.2_2 will be limited to an 2242 M.2 SSD.)