After you are done cloning, you should remove the old drive. It may work perfectly without doing anything since it will be your new "C" drive. However, when you restart, you should go directly to the BIOS. There is a section called "Boot Order". Set the optical drive first , then the new SSD. IF the old HD is still in the list, de-select or remove it.
The reason you put the optical drive in front of the SSD ( in boot order ), is on the rare occasion you have a boot problem with the main OS, the system will automatically check first to see if you have the Windows rescue disk or OS disk in the optical drive for repair.
If this makes you uncomfortable, you can "restart" now and keep pressing the "delete" key , once a second ( a slow tapping ) until the BIOS comes up. You can explore the BIOS without making any changes, just find the Boot Order section and check it out without actually doing anything. Even if you accidentally make a change it will always ask you if you want to save the changes. Use the "Esc" key to back out of anything in the BIOS. It's not that scary!