The point of having the SSD is for speed. Windows on it is, but if ALL your other programs are on the hdd it won't feel much faster. On my build I have windows, my AV, firefox, VLC/GOM, etc. Last I used it, some programs like Openoffice will want to install some parts on the OS partition/drive. Another thing to consider is 32GB drives aren't very fast. You don't normally see the top speed until you get to the 128/256GB drives. The more memory chips, the faster the speed.
Best answer has been picked, and you've heard the advice so I'm closing now. I hope you're happy with your pick.