Your best bet would likely be to go with an identical kit, but be aware that even then they may or may not play together nicely. Memory sticks that are sold together in a kit have been tested by the manufacturer and are guaranteed to work together, but there's no such guarantee with two kits purchased separately, even if they're the same brand and model number; memory can be very finicky that way. (It isn't always, but the only way to be sure with any given sticks of memory is to try it.)
If you plug in a second kit and it doesn't want to work, the big guns here may be able to help you adjust the timing to get it running, but again, no guarantees.