No, it's not worth it. That boosting behaviour is the secret behind it's remarkable energy efficiency, AMD called it a 'rush to idle'. Get the work done fast and put the core back to a deep sleep state as frequently as it can.
The best curve I've found for my 240mm AIO is a low, barely audible fan speed up to 65-70C then rising to audible but not annoying around 85C. Only when it gets to 90C does it get annoying...by 95 it's close to maximum fans. I'm using a 240mm AIO and take advantage of the enormous capacity of the liquid to absorb heat before letting the fans go crazy to dissipate it faster through the radiator.
But I also set a platform thermal limit at 90C for my 3700X CPU so it can't ever get there.
One other thing is that 5900X CPU's are fully expected to hit up to 90C in routine use, and it's by design. AMD has told us that in various interviews around launch time. I'd expect that with temp spikes. Otherwise, it's very good to see AVERAGE temps lower, in the 70's if possible, since it keeps the CPU boosting at higher clocks. But AVERAGE temps in the 80's would not be unexpected in extreme all-core workloads heavy with AVX instructions like rendering and transcoding.
If you're using PBO look for the platform thermal limit setting and put it in the 85-90C range.