First, thanks for Best Solution.
The on-line manual for your mobo does not show any details of what its configuration options are in Hardware Monitor, so I can only write about "typical" items. One is the MODE - that is, the type of electrical signals the header sends to the fan to control its speed. Normally these include Voltage Control Mode (aka DC Mode), and PWM Mode. DC Mode is for 3-pin fans, PWM for 4-pin fans. Then there's a PROFILE choice for how the system makes the decision of what the speed should be. These normally include "Standard" or "Normal" which uses a default "fan curve" of speed (actually, a % of full power) versus TEMPERATURE measured at the relevant sensor, whether the details of that curve are shown or not; "Turbo" for constant full speed; "Quiet" for constant slow speed; and "Custom" in which you get to specify your own "fan curve" for automatic control based on temperature. Sometimes there's an overlap in terms here. Some systems use the display of the fan curve both to show you what it will do by default and to allow you to move those points to create your custom curve. Some will use the label "Manual" in place of "Custom" to indicate that this lets you manually set the fan curve. Others may use the term "Manual" for an option that lets you specify one fixed speed (not the same as Turbo or Quiet). This last sounds like what you have done - one fixed speed all the time. On other systems that use a custom-specified fan curve, you can accomplish virtually the same thing by specifying the SAME speed for all temperatures.
That "Smart Fan Curve" option sounds like what I called "Standard" - that is, it uses a default "fan curve" that DOES alter the fan speed according to temperature. You used that for the CPU cooler. Is the same option available on your SYS_FAN headers? If so, use that for them, and verify that these headers are using the motherboard temp sensor, not the one in the CPU chip.
You SHOULD have the fan speeds adjusted for you automatically according to temperature. That way they will run fairly slowly when your workload is low, and speed up for heavy workloads. Using a fixed speed may mean the fan noise is low, but YOUR comfort with noise should NOT be the aim. The aim should be the TEMPERATURE of your system components so they are cooled properly at all times and last longer. In extreme cases of high workloads with inadequate cooling by slow fans, the system MAY get so hot it slows itself down to protect it. Then you have MUCH reduced performance so your fan can keep quiet - not a common strategy!
In general, and especially when starting out, I suggest the default fan curve is the right choice. Consider the alternative: how do you decide what IS a better choice? You do not have any info on what the real temperatures are over MANY mobo components, nor of what those SHOULD be. In that case, some try for extra caution and set a custom curve to do MORE cooling than the default at all temperatures. The only downside to that is VERY slightly less lifetime for fans you CAN replace after several years. But setting it for LESS cooling than default I consider risky.