Question Will nitrile gloves protect you from electric shock while working on power supply?

No.

(Edit: to add) Also NEVER work on a live system, more people die from 120/110VAC than any other voltage. If you have to ask these questions I do not advise you do the work without familiarizing yourself with electrical safe work practices. You could harm yourself or others inadvertently.

I am an electrician. No, I will not advise further.
 
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