13thmonkey :
the radiator is so remote from from the CPU block that it doesn't matter, all it controls it whether you can get the temp of the fluid entering the block back down to a useful temp, and lets say that you can. Lets go into the calcs in more detail at the block:
The block might hold 2ml of liquid, so that's 2g of water, and about 1.6g of alcohol. And for now assume a flow rate of 2ml/s
On a 65W processor in 1 second that would heat up the water by 65/4.2/2 = 7C, for the Alcohol the rise is 65/2.4/1.6 = 17C, so assuming an ambient of 30C for the liquid (close to case temp) you'll have water leaving the block at 37, and alcohol leaving at 47C. The Water entering the rad is at 37, and the alcohol is 47.
Both will lose some heat in the rad, but the alcohol in the block has much less thermal headroom before it boils, so if the rads don't get the alcohol down to 30 again, then you'll start to get the exit temps from the block climbing much quicker than for the water, and if it hits 78C, it will boil.
You have the additional problem that locally in hotspots in the block with a die temp of 70+C it will get very close to 78C, and it will boil. With water this can only happen if the CPU has hit it's throttle temp.
wrong , Alcohol will lose heat faster in the radiator than water , you need to calculate that right them we can agree or not.
I am not saying you are wrong by the way , I am just saying you are not calculating it right. also , in Alcohol the length of loop is a huge factor in cooling unlike water , because it cools down faster ...
one more thing to add , The alcohol loop should be vertical and not horizontal , so in case there is a Vapor between the CPU and RAD , it will move up ...
anyways I am thinking more about Ammonia now , I will see what I can find online.