If you want 2 slots to work with x16 lanes, then none of the boards support that. As soon as you install the second card, the lanes will get divided. That is because, the board only has so many lanes in total. Usually it is 24 for the z series. Besides, SLI is not recommended any more. There are only a handful of games that support it nowadays.
mATX board is smaller than ATX, it will fit easily. But, not the other way around.