While graphics drivers and third-party utilities allow you to overclock your graphics card's GPU and memory, pixel shader clock speeds can only be increased through the card's BIOS.
http://www.tomshardware.com/2007/11/23/overclock_your_graphics_card_in_five_minutes/index.html
http://www.tomshardware.com/2007/11/23/overclock_your_graphics_card_in_five_minutes/index.html