If the Windows is on any either SSD or one of the disks it would affect speeds. Repositioning while writing will decrease the performance drastically. Things like the a downloader running in parallel for example.
What brand model SSD? The initial high speed could be because of RAM caching and then it drops down. However, the sustained copying speed I think should be more than 1-2Mb/s, from any single SSD to any single HDD (not RAID).
When dealing with RAID5 one can expect a penalty and occurrence of write amplification.
Parity RAID adds a somewhat complicated need to verify and re-write parity with every write that goes to disk. This means that a RAID5 array will have to read the data, read the parity, write the data, and finally write the parity. That is a total of four operations for each effective one and this means a write penalty of four on RAID5.
One more thing is that write speed of a RAID5 depends upon the controller implementation heavily. RAID software and the actual controller play a role. I said software because you didn't mention a RAID card or the presence of a RAID controller on the motherboard.