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Question Moving windows to new pcie ssd?

how would i transfer my windows over
Perform cloning.
You can use Macrium Reflect or
Minitool Partition wizard or
Samsung Data Migration (for Samsung drives only) or
some other cloning software.

You'll need both - clone source and clone target drives connected simultaneously.
Since your board has only a single M.2 slot, then you'll also need
either PCIE M.2 adapter or USB M.2/NVME adapter.