first make sure that the video cards are being fed by the larger +12v rails, that would be 3 and 4.
see if that makes a difference
Then, try running just one video card for a while and see how that goes.
pull one card out then benchtest for 24 hours, remove that one, replace with the other. retest for another 24. If you get no failures, that points to three possibilties
1. second pci slot is possibly bad - a remote possibility
2. your power supply just cant handle the load on a particular rail - switch to a single rail type.
3. possible overheating in a particular area or chip that only happens when both cards are installed. two cards of this size will generate HUGE amounts of heat
and the PSU also puts out huge amounts as well. try running with the case open maybe put a fan blowing in cool air. retest.
BTW - is your PSU , certified for this configuration?
check here- http://game.amd.com/us-en/crossfirex_components.aspx?p=3#ATI%20Radeon™%20HD%204870%20X2