The tiers are kinda important, but mainly as a source of reference. A tier2 platinum will have better efficiency and maybe even better output ripple suppression than a tier1 gold unit, but is rated tier2 simply because some of the internal parts are not of the highest quality. A good example is the older corsair RM 750. Built by Chicony, it was excellent quality build, amazing outputs on par or better than Seasonic X, yet ranked tier4 because of thermal properties causing shutdowns under maximum load conditions. So there's that to consider.
High OC is all about stability, mainly voltage regulation. You won't get stable OC of 5GHz on a unit with funky v-droop and uneven ripple. For that, a tier1 unit is more purposed, but regardless of tier, the units showing consistent quality ripple suppression take precedence. The G2 is slightly better off there than the GS.
It's a psu, that you will demand top performance from. You will, by necessity, need to pay a premium for that. Don't skimp, its just not worth it.