Look at the motherboard memory specifications and User Guide/Manual.
There should be some very specific information about the accepted memory configurations. Order of slots being filled. How the modules are paired. Where the fastest modules should be located. May require some matching BIOS setting.
Some memory module combinations will work and other combinations will not work or any "extra" memory may just be ignored.
Confirm that you have a valid installation. Then verify that the existing modules are all correctly and fully seated.
Check the BIOS settings. You may need to configure some memory settings therein.