Helpstar and CountMike above have given you great ideas. Maybe this can help you with the details. Helpstar's comment may explain why the fan now is trying to run slower and that causes it to stall sometimes. CountMike points to how to fix that.
Go into BIOS Setup (p. 25 of your manual). Use the F6 key to get to the SmartFan screens (p. 26), choose the particular CHA_FAN header where you have that rear fan plugged in, then make these settings using the drop-down choosers at upper right.
1. CHA_FAN Speed Control to Normal.
2. Fan Control Use Temperature Input to Motherboard
3. CHA_Fan Control MODE to Voltage IF that fan has 3 wires and pins in its connector, OR to PWM if the fan is a 4-pin type
4. CHA_FAN Stop to DISabled so it never stops
5. Fan Fail Warning to ENabled so you do get a warning on-screen if the fan stops
By the way, those same settings should be used also for the other CHA_FAN header where you have your three front fans plugged in.
Use the Esc key back to the Main Menu, then F10 to get to the Exit Menu (p. 43)
There choose Save & Exit Setup to save your settings and reboot. See if that makes a difference.
If this still allows your rear fan to stall, go back into BIOS Setup, select that fan header, and make this adjustment. First, note that graph of fan speed versus temperature. Now change the CHA_FAN Speed Control to Manual so you can set your own version of the fan curve. In the table of values across the bottom make it the same as it was in the original "Normal" Profile. Then for the first (lowest temp) point on the graph change the PWM value to something a bit higher, like 30%. This will ensure that the fan at its slowest speed never goes slower than that setting. That should prevent it from stalling at the coolest temperature. Again, use the Exit Menu to Save & Exit Setup.