1) depends on the cpu cooler. With a tower style cooler, air is drawn in the front and most of it is shoved out the back, right at the rear exhaust area, so a rear exhaust fan is somewhat important as far as directly pulling that hot cooler exhaust straight out of the case. If the fan can't keep up with what's coming from the cooler, the heated air stays in the case. The top fan should help that process. If the top is pulling too much air, then you get lesser air all the way through the cooler, more ends up bleeding out the top side, makes the cpu run hotter because of lack of efficiency.
With a downdraft type cooler, top fans are great, heat rises naturally, so air is moving in that direction anyways, added to by the gpu exhaust rising. A rear exhaust can often hinder that process as it's trying to pull that warm air 90° sideways.
With an aio, doesn't matter, air is being pushed to the corner anyway by the intake fans on the rad.
Case airflow is all about 1 thing, air Flow. What is it doing, where is it going, where isn't it going. Fan types play a major role there. Airflow/cfm fans move a Lot of air, but it doesn't go anywhere, it's air volume. Static pressure fans Move air a lot, smaller volume, more force. 3x LL's at front are pushing air to the gpu. This is a good thing. The AER in back is exhausting that air, doesn't need pressure, it needs to move volume.
Lowering volume moved, by adding the LL at exhaust might look good, but looks is not performance, the LL's just move a little, hard. But at exhaust, nobody cares how hard the air is or where it goes, it's outside the case.
2) The NF-P14 is a balanced fan. Less volume than the AER but stronger pressure. Excellent for intakes, ok for exhaust. At less than 100% it'll move @ the same air volume as the AER, close enough to make no difference. What will make a noise difference is the seperate header and adjusted fan curves. You'll want the LL at high rpm, @ 1200±, you'll only want the top exhaust at @ 900 rpm±. Regardless of AER or P14.
Personally, I'd go with Arctic F, just as quiet as either Noctua or AER, move the same amount of air, half the price.