mechan :
The additional VRAM usage was unnecessarily addressed. That shows that, despite the fact that a program can use more VRAM than a graphics card has, there is a certain amount of used VRAM that the program didn't actually need to be using in order to perform without sacrificing textures, resolution, or AA.
--->M-Y-S-T-E-R-Y<---
See
Part I, and the sheer amount of memory that the windows desktop manager uses (up to 410MB on Win 8.1 at 4k). Those assets would normally stay in graphics memory, but can be paged out while gaming full-screen with little or no issue. That alone can explain what you see in your charts - essentially the 780Ti pages out windows desktop manager assets, while the Titan does not need to.
Wouldn't make a difference on FPS, but would explain the behavior you describe. Might not be -the- answer, but is certainly a possible hypothesis.
What it does NOT explain is the higher usage of the Titan with no AA involved, which honestly makes me question those measurements - I did similar measurements across cards and saw nothing of the sort of a 400 MB usage different. Something else is fishy with those tests you posted ...