Fred, that's not how that works, positive/negative pressure. It's really, seriously abused, almost as much as bottlenecking, and just as misunderstood.
A fan blade moves through air, which creates a low pressure area behind the blade. The result is a higher pressure exhaust. Spin the blades fast enough and you get a lower pressure area in front of the fan. Nature abhors a vacuum, so case air will move to fill that low pressure area constantly, resulting in airflow. Air, like electricity, always follows the path of least resistance, and the strongest draw is the area closest to the fan. So air on a rear exhaust will come from the top vents, pcie slots, case etc. The job of the intake fans isn't just to replenish air, but also to overcome the tendency of the exhaust fan to pull air from outside sources. At low rpm, not much air is moved in from the intakes, so at idle speeds you'll have a negative pressure system as the rear exhaust is still pulling outside air. At loads/high rpm, there's enough cfm moved in that the path of least resistance to airflow is using case air, so a positive pressure system. The exhaust doesn't pull unfiltered air much at all.
Your psu fan spinning has absolutely nothing to do with negative/positive pressure. It's relegated by temps under load. It's operated by a thermistor circuit inside the psu. If the load isn't sufficient to create enough heat, the fan doesn't kick on. If the load is sufficient, there's enough heat generated that the fan does kick in. There's simply not enough pressure generated by input fans to force air through a psu