Just because similar RAM with given timings is stable, doesn't mean that yours is.
But if you want to tinker, then this short video tells you how to manually OC the RAM;
View: https://www.youtube.com/watch?v=Yed-a9vqTYc
For the most part, with RAM OC, idea is to get the lowest latency in nanoseconds and not the highest transfer rate.
Marketing.
For example, street legal cars have the top speed presented boldly, e.g 200 km/h, 250 km/h, 300 km/h, 330 km/h etc, but why make cars to go that fast, when speed limit is 90 km/h or 120 km/h? Since you'd never be able to drive that fast regardless.
(Similar is with car engine RPM, most cars keep the RPM below 3000 (gasoline engine) when driving daily, so, it's pointless to make engine that can go 7000-9000 RPM.)
But bigger number usually indicates that "it has to be better" and people want to get bigger number item. Be it RAM transfer speed, car top speed or max engine RPM. Despite never using the hardware at it's fullest capacity.
As for RAM, look your MoBo memory QVL and see if there is actually any RAM that can operate at 5133 MT/s.
Link:
https://www.msi.com/Motherboard/PRO-Z690-A-DDR4/support#mem
I gave it a look and there is just 1! RAM set, from Kingston, that your MoBo can run at 5133 MT/s.
Well, at least this is the one that MSI tested and was able to get working at 5133 MT/s. (Having a guarantee.)
I couldn't find what that specific RAM set costs since it's Unavailable at current date. Not even when looking back up to 2 years. But given that normal DDR4 usually caps out ~3200 MT/s, that 5133 MT/s set could've easily cost 1000 bucks, if not more.
E.g similar DDR4 kit (2x 8GB) at 5100 MT/s costs 1000 bucks,
pcpp:
https://pcpartpicker.com/product/DL...-x-8-gb-ddr4-5100-cl19-memory-blm2k8g51c19u4b
While the same capacity (2x 8GB) at 3200 MT/s costs 26 bucks,
pcpp:
https://pcpartpicker.com/product/P4...8-gb-ddr4-3200-cl16-memory-sp016gxlzu320bdaj5
That's price difference of
38.4 times! It is insane how much the 5100+ MT/s DDR4 RAM costs.