^ This is the QS1 sample (C0 stepping) - they should be much less problematic on any decent board as they should be virtually identical to the final silicon except some very small tweaks (ehm... VT-d)
ES2 is one generation earlier, and it has somewhat more differences.
Anyway, it could be PCIe - the EFI boot sequence goes as follows: 67 --> 69 --> 5A
69 is System Agent DXE initialization - system agent in SB-e holds PCIe controller as well... but I can't be really sure at this point what is the problem actually.
In normal circumstances, after 69, the board should progress to 6A -> system agent SMM initialization, and this happens in the, say, ASUS P9X79 Pro board without problems. But with Z9PE-D8-WS, it is just stuck before that.