Let me clarify then..
yes it is possible to stop the heart with only 100milliamps depending on the voltage.
But if you jam your screwdriver into the voltage regulator capacitors.. that voltage will go through the screwdriver not your heart. (path of least resistance) and even if you had your fingers right near the tip, it will burn you not stop your heart.
But a better reason.. if you dont know which connection to close dont jam your screwdriver in there because you will DESTROY the board.
----------
Ok, sorry about that little tiff.
The safest/easiest way to test the switch is actually to just short the connection on the switch side.
You wont need to put your fingers anywhere near the board, just make sure that you close the connection between the two wires.
If that doesnt work it means your switch isnt the problem.
This could mean there is a problem with the power supply, it could also mean there is just a problem with a voltage load on the mobo.
1. turn off the power switch on the power supply or unplug it if it doesnt have a switch.
2. Remove any USB cables with external power.
3. Wait 60 seconds
4. Hold down the power button for a few seconds.
5. plug the power back in and try again.