cbrunnem :
assuming it helps im just trying to figuring out why
assuming?
I have not set out to lie to anyone here regarding all that I discover and share, if I tell you something is working, it's working!
Or I would not be doing it!
Trapped air is an insulator not a conductor, that's why trapped air was initially used in the beginning of cheap therma pane glass.
A layer of air was sandwiched between 2 layers of glass with moisture absorbing beads in the outer rim channeling, air did not turn out long term successful, because the moisture beads over time lost their moisture absorbing effectiveness, and water would form between the glass, so they substituted the air for argon gas.
Trapped air in your thermal compound between your heat sink and CPU or GPU is bad, it becomes an insulator instead of a conductor, in the same respect the air in the cooler could never become as cold as the water, as you say, simply because there is more heat outside the cooler than cold inside.
i feel like the air would eventually cool to the water temp....
The air itself becomes an insulator between the water and the larger area of inside walls of the cooler itself, the more air space there is, the larger area the air is contacting, and the larger area is not as cold as the water layer is,
so the air will never get to be the same temperature as the water.
The insulation layer floating on the water simply isolates the water from the insulating air, allowing the colder temperature of the water to remain in the water longer.
And it works!
Understand?
The large cooler was very effective when I was running 10 gallons of water, the thermal mass of the water was larger than the air space left inside the cooler, dropping the water level in such a large cooler reversed that effectiveness and brought problems to the table that had to be resolved to retain as much cooling efficiency as possible.
I could have simply gone to a smaller cooler, but I am testing out this peltier solution to see if it is long term viable, so the insulation layer allows me to mimic a smaller cooler.
There is no sense in me wasting money buying a smaller cooler if the entire thing is possible to be accomplished as a closed loop using a standard 2 bay reservoir, which I already have in my possession, with the peltier assembly taking the place of the radiators.