If your mobo is not mounted in your case yet, the stand-offs are NOT your problem currently. But you really should look at that post I cited for after you do get the system working OUT of the case.
Breadboarding is a troubleshooting technique. It is named that way because you place your mobo and components on an insulating surface like a dry wooden board. Emphasis on INSULATING so not short circuits.
One item caught my notice. Many mobos are set up to protect the expensive CPU chip from damage caused by poor CPU cooling. There MUST be some cooling device like a fan plugged into the CPU_FAN header, and it MUST start up right away when power is turned on. If that header gets NO fan speed signal back from its fan (or pump) it may simply refuse to allow any start-up.
The starting point for this style of troubleshooting is to have the mobo on a safe surface and mount in it only these items:
1. CPU WITH its cooler connected to the CPU_FAN header
2. ONE stick of RAM - check mobo manual for the correct slot for a single stick
3. Power supply to mobo from the PSU, inlcuding any power connector for the CPU chip
4. Cable connected from mobo video output socket to a monitor IF your mobo and CPU chip provide on-board video output, and no extra video card in a PCIe slot. HOWEVER, IF you MUST use a video card because the mobo cannot do this, then install a card in a PCIe slot and connect to that.
5. NO SSD in a mobo socket, NO HDD attached by cable to the mobo ports, NO keyboard or mouse attached.
6. NO connection to case controls and cables.
7. It can be helpful if you get a small "speaker" unit designed to plug into the SPKR pins of your mobo's Front Panel header. During start-up the mobo can send out sounds by these pins only with "beep codes" indicating success or trouble codes.
8. To "turn on" use a small screwdriver to short together briefly the two pins of the Front Panel header marked for the case Power Switch wires. Brief contact is enough - do not try to keep the pins shorted together.
With this set up what SHOULD happen is that the mobo does go through a start-up sequence with its CPU cooler fan running and produces messages on the monitor screen about its progress until it tells you there are errors like no keyboard and no mouse and no Boot Device. If you get that, it is all working correctly and you can shut down, add ONE component to the board, and try again. As long as it succeeds, keep up this process. When it fails, you know which new componenet caused that.